Disposable cylinders represent a significant risk to port workers and support a black market in counterfeit refrigerants.

In 2011, several refrigerated, reefer containers exploded, killing three port workers. While there has been no further tragedies since then, counterfeit refrigerants remain in circulation and still represent a significant safety risk.

Counterfeit refrigerant cylinders typically consist of a dangerously unstable cocktail of gases, blended to roughly mimic the most common refrigerant, R-134a. These cylinders are often loaded with rogue gases such as R-40. Though similar to R-134a, R-40 reacts with aluminium to form trimethylaluminum, a highly volatile substance that, when exposed to air, can explode. At best, these fake refrigerants perform poorly, are energy-inefficient and are likely to damage hoses, seals and compressors. At worse, they are highly toxic, and in the case of the fatal accidents in Vietnam, China and Brazil in 2011, highly volatile.

According to international insurer TT Club, R-40 contamination accounts for 0.2% of the world’s reefer container fleet, affecting about 2,500 reefers. However, other counterfeit refrigerant mixtures, such as those containing R-50, R-744, R-22 or R-170, are also considered unsafe, so the number of reefers affected could be far higher.

Disposables a permanent problem
Some operators may be unaware of the potential risk of using counterfeit refrigerants, while others may be seeking to cut costs. However, the main reason these refrigerants continue to circulate is because of the continued existence of disposable cylinders. According to Svenn Jacobsen, Technical Product Manager, Refrigeration, Wilhelmsen Ships Service, the absence of a worldwide ban has created a robust market for counterfeiters. “These cylinders are the container of choice for the counterfeiter,” he says. “Cheap and untraceable, no counterfeiter is ever going to get any complaints from their customers using this type of packaging”.

Jacobsen explains that counterfeiters offer what appear to be authentic, trademarked refrigerants. Despite the efforts of leading manufacturers such as Honeywell, Linde and Dupont, which have taken legal action to crack down on counterfeiters and changed packaging to discourage fakes, counterfeit refrigerants remain an industry menace. Even elaborate precautions, such as holographic seals or cylinder stamps, are easily copied in days rather than months. For Jacobsen, the only way to put an end to this illegal and dangerous market is to ban disposable cylinders.

“If the legitimate refrigerant suppliers no longer provided refrigerants in disposable cylinders, the counterfeiters would be out of business,” he says, noting that WSS does not offer refrigerants in disposable cylinders. “We don’t support their use and we believe a worldwide ban is far overdue”.

Whether or not a global ban on disposable cylinders will come into force anytime soon is unclear. In 2007, the European Union (EU) banned disposable refrigerant cylinders in the EU and on EU flagged vessels. Similar bans are also in place in Canada, India and Australia. However, disposable refrigerant cylinders are still in use elsewhere in the world.

Unintended consequences
More recently new EU legislation, introduced in January of this year, may only exacerbate the issue. The new EU regulation applies to the use of hydrofluorocarbon (HFC) R-134a. HFCs are fluorinated greenhouse gases (f-gases) with a relatively high Global Warming Potential (GWP). So while R134-a is an ozone-friendly, chlorine-free, energy-efficient, low toxicity refrigerant, its use accelerates climate change. The EU regulation (EC517/2014) calls for the total supply of HFCs across the EU to be reduced to just 63% of the 2009-2012 baseline quantity by 2018, measured as the total tonnes of carbon dioxide equivalent (CO2e). This sustained reduction in capacity will continue until it reaches just 21% of the original baseline figure by 2030.

While Jacobsen applauds the EU’s bold move to reduce the environmental impact of R-134a refrigerants, he cautions that these regulations may inadvertently create a strong market for suppliers of counterfeit refrigerants. “It is likely that the reduction in the supply of EU HFCs will lead to shortages and a sharp spike in costs, meaning some operators will be tempted to purchase lower-price refrigerants,” he says. “This regulatory change will create an ideal market for counterfeiters. Despite numerous warnings, accidents and fatalities, many operators will be more willing to take a chance on gases packaged in disposable cylinders by unregistered suppliers. We anticipate that the counterfeiters of R-134a are going to be very busy in the years ahead.”

If it seems too good to be true…it is
In the absence of a global ban, it is up to operators to use common sense, coupled with a healthy dose of scepticism. Because fake refrigerants are found exclusively in disposable cylinders, Jacobsen recommends that operators only purchase refrigerants supplied in refillable, re-usable, traceable cylinders. For operators who insist on using disposable units, they should make sure a reputable company, which has been audited and approved by a licensed manufacturer, is supplying their refrigerants.

Jon Black, Global Head of Chemicals and Refrigerants, Linde Gases, suggests that operators only source refrigerants from well-known providers or companies who distribute the products for these main manufacturers. “If a new distributor appears on the market, we recommend operators conduct a thorough audit before making a purchase,” he says.
Finally, if the price quoted for gases is way below the market average, it is likely to be a counterfeit. It may be a cliché, but you really do get what you pay for. So if you want a safe, consistent, and authentic refrigerant you must be willing to pay for it.

R134a and low GWP replacements
Operators active in the EU will have to manage the new regulations that apply to apply to the use of hydrofluorocarbons (HFC). The so-called ‘drop-in’ replacement for R-12, R-134a is the most used refrigerant in refrigerated shipping container units accounting for approximately 80% of the market.

Contributing to global warming when released to the atmosphere, R-134a has a GWP value of 1430.

With GWP calculated as: GWP = heat trapped per lb. of greenhouse gas
heat trapped per lb. of CO2

There are of course potential replacements for R-134a readily available such as R-1234yf, which has a GWP of four or R-744 (CO2), which has a GWP of one. However, switching to such ultra-low GWP alternatives will typically require converting existing equipment or installing new equipment specifically designed to use lower-GWP refrigerants. In addition, these low GWP refrigerants also currently come with a cost premium attached.

For further information, contact:
Svenn Jacobsen
Technical Product Mgr. Refrigeration
Wilhelmsen Ships Service
svenn.jacobsen@wilhelmsen.com
Main Line: +47 6758 4550
Mobile: +47 4814 9720

Wilhelmsen Ships Service is part of Wilhelmsen Maritime Services, a Wilh. Wilhelmsen group company. It has the world’s largest maritime services network, with 4,500 marine professionals servicing 2,200 ports in 125 countries. Wilhelmsen Ships Service supplies safety products and services, Unitor products, Unicool refrigerants, Unitor and Nalfleet marine chemicals, maritime logistics and ships agency to the maritime industry. Last year the company made product deliveries to 25,000 vessels and handled 70, 000 port calls. For more information, see wilhelmsen.com/shipsservice